| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765796 | Polyhedron | 2014 | 7 Pages |
Abstract
Mechanistic studies of PdII-mediated allylic acetoxylation suggest that O2 and benzoquinone promote C-O bond formation by different pathways: BQ participates directly in C-O bond formation via an oxidatively induced reductive elimination pathway, while O2 traps Pd0 following reversible C-O bond formation from an allyl-palladium(II) species.132
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Tianning Diao, Shannon S. Stahl,