Article ID Journal Published Year Pages File Type
7765806 Polyhedron 2015 7 Pages PDF
Abstract
Three new Cu(I)-thiol complexes of cysteamine, cysteine and 2-mercaptonicotinic acid were prepared. According to DFT calculations they show dimeric structures with differently distorted Cu2(μ-X)2 cores (X: Cl, I) and displaying short cuprophilic Cu⋯Cu contacts. An additional thiolate-Cu(I) derivative also shows dimeric structure with two antiparallel linearly arranged N-Cu-S moieties.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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