| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7765870 | Polyhedron | 2014 | 5 Pages |
Abstract
The titanium alkylidene-triflate complex (PNP)TiCHtBu(OTf) was found to promote N-N bond cleavage of 9-diazofluorene and ditolyldiazomethane to give the imido complexes, (PNP)TiN[C13H9](OTf) (1) and (PNP)TiN[CHtolyl2](OTf) (2), along with free NCtBu. A mechanism to the N-N bond cleavage of the diazoarylalkane is presented.
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Physical Sciences and Engineering
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Authors
Jun-ichi Ito, Marco G. Crestani, Brad C. Bailey, Xinfeng Gao, Daniel J. Mindiola,