Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7765876 | Polyhedron | 2014 | 10 Pages |
Abstract
Two isomeric tetradentate chelates have led to disparate chemistry with iron: Fe{N(TMS)2}2(THF) catalyzed the cyclization of Me2C(CNCH2(2-py))2 to 4,4-dimethyl-2-(pyridin-2-yl)-N-(pyridin-2-ylmethylene)pyrrolidin-3-amine, whereas Me2C(CH2NCH(2-py)2 (dmp(PI)2) generated {dmp(PI)2}FePMe3 (Fe-PMe3) when treated with (Me3P)3HFe(η2-PMe2CH2).96
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Elliott B. Hulley, Valerie A. Williams, Wesley D. Morris, Peter T. Wolczanski, Kenneth Hernández-Burgos, Emil B. Lobkovsky, Thomas R. Cundari,