Article ID Journal Published Year Pages File Type
7765876 Polyhedron 2014 10 Pages PDF
Abstract
Two isomeric tetradentate chelates have led to disparate chemistry with iron: Fe{N(TMS)2}2(THF) catalyzed the cyclization of Me2C(CNCH2(2-py))2 to 4,4-dimethyl-2-(pyridin-2-yl)-N-(pyridin-2-ylmethylene)pyrrolidin-3-amine, whereas Me2C(CH2NCH(2-py)2 (dmp(PI)2) generated {dmp(PI)2}FePMe3 (Fe-PMe3) when treated with (Me3P)3HFe(η2-PMe2CH2).96
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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