Article ID Journal Published Year Pages File Type
7766069 Polyhedron 2015 9 Pages PDF
Abstract
Nano Sb2S3(20 nm) and (Tl+2/3−2δ)[Tl3+1−ySb3+y]Sb2O6O′1/3−δ, a pyrochlore, have been prepared from three antimony(III)-dithiocarbamate precursors and have been characterized by PXRD, FESEM, EDX, HRTEM and SAED. The dithiocarbamate precursors show distorted octahedral and pentagonal pyramidal geometries around antimony. CShM analysis of the structural data support the distorted geometries.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Metal dithiocarbamate precursors for the preparation of a binary sulfide and a pyrochlore: Synthesis, structure, continuous shape measure and bond valence sum analysis of antimony(III) dithiocarbamates
Authors
, , ,