| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7766102 | Polyhedron | 2015 | 9 Pages |
Abstract
[Fe(5-Cl-qsal)2][Ni(dmit)2]·2MeCN was prepared. The magnetic behavior is described as the sum of the contribution of alternating chains of anions (with strong antiferromagnetic intrachain coupling) and chains of cations presenting a spin-crossover process. Structural constraints lead to a two step SCO transition and the appearance of a disordered intermediate phase.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Crystal structure and spin crossover behavior of the [Fe(5-Cl-qsal)2][Ni(dmit)2]·2CH3CN complex](/preview/png/7766102.png "First Page Preview: Crystal structure and spin crossover behavior of the [Fe(5-Cl-qsal)2][Ni(dmit)2]·2CH3CN complex")
Authors
Bruno J.C. Vieira, Joana T. Coutinho, João C. Dias, José C. Nunes, Isabel C. Santos, Laura C.J. Pereira, Vasco da Gama, João C. Waerenborgh,