| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7766302 | Polyhedron | 2014 | 5 Pages |
Abstract
Four oxorhenium(V) complexes 3a-d equipped with naphtholate-oxazoline based ligands 2a-d have been prepared and characterized by NMR, IR and mass spectroscopy as well as elemental analysis. The molecular structures of complexes 3b and 3d have been determined via single crystal X-ray diffraction analysis and both display a distorted octahedral geometry. Complexes 3a-d are active catalysts for the epoxidation of cyclooctene with tert-butylhydroperoxide (TBHP) showing moderate conversions between 41% and 65%.
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Belina Terfassa, Jörg A. Schachner, Pedro Traar, Ferdinand Belaj, Nadia C. Mösch Zanetti,