| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7766402 | Polyhedron | 2014 | 8 Pages |
Abstract
Theoretical studies predict diverse structural features in the binuclear cyclobutadiene manganese carbonyls (C4H4)2Mn2(CO)n (n = 6, 5, 4, 3). Some such structures are related to experimentally known or low-energy theoretical Mn2(CO)n+4 or (η5-C5H5)2Cr2(CO)n structures. Other (C4H4)2Mn2(CO)n structures contain novel features such as agostic hydrogen atoms forming C-H-Mn bridges or central elongated octahedral Mn2C4 cluster units.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Xiaohong Chen, Quan Du, Rong Jin, Hao Feng, Yaoming Xie, R. Bruce King,