Article ID Journal Published Year Pages File Type
7766557 Polyhedron 2013 4 Pages PDF
Abstract
Light-induced valence tautomarism (LIVT) of [Co(phen)(3,5-DTBSQ)(3,5-DTBCat)] (1) was investigated by ESR of the semiquinonate radical both in powder sample and in glass matrix. The ESR signal decay and the relaxation in the glass matrixes were well analyzed by double exponential fitting, indicating the possibility of two-step mechanism.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
ESR study of light-induced valence tautomerism of a Co mononuclear complex: [Co(phen)(3,5-DTBSQ)(3,5-DTBCat)]
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