Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
77723 | Solar Energy Materials and Solar Cells | 2015 | 10 Pages |
•Energy spectrum in quantum dots (QDs) is approximately calculated.•Sub-bandgap photon absorption coefficients in QD IB solar cell are calculated.•Two Hamiltonians used: the new EKPH and the well recognized LKPBH.•Calculations 100 times faster with the EKPH.•EKPH adequate for feedback in design with device engineers.
The calculation of the energy spectrum and absorption coefficients of quantum dot nanostructured intermediate band solar cells using the Empiric K·P Hamiltonian method and its agreement with experimental data are summarized. The well established Luttinger Kohn Hamiltonian modified by Pikus and Bir for strained material, such as quantum dot arrays, is presented using a simplified strain field that allows for square band offsets. The energy spectrum and absorption coefficients are calculated with this new Hamiltonian. With the approximations made the energy spectrum results to be exactly the same but the absorption coefficient fits experiments less accurately. The computer time using the latter Hamiltonian is much longer than the former one.