Syntheses, density functional and sparkle PM6 semi empirical theoretical studies of O,O′-dialkyl/alkylenedithiophosphate derivatives of tin(IV) phthalocyanine adducts

Novel tin phthalocynine complexes bearing O,O′-dialkyl or alkylenedithiophosphate were synthesized in 1:2 molar ratio and being well defined, experimentally and theoretically employing the hybrid B3LYP functional. Fukui Functions were estimated in attempt to rationalize the hydrolysis outcome of the prepared complexes.177