| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7810536 | Journal of Molecular Structure | 2013 | 5 Pages |
Abstract
The reaction of cobalt chloride with p-tert-butylthiacalix[4]arene (H4TC4A) and 1,3-di(4-carboxyphenyl)benzene (H2DCPB) in solvothermal condition results in a novel calixarene-based compound H{[Co4Cl(TC4A)](DCPB)2}. The compound was characterized by single crystal X-ray diffraction, EDS analysis, TG analysis and IR spectroscopy. The structure was featured with some zigzag chains containing the coordination nanotubular channels, which are constructed by bridging the shuttlecock-like Co4-TC4A secondary building units (SBUs) with the V-shaped DCPB ligands. In order to evaluate the porosity, the N2 sorption measurement was carried out.
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Authors
Mei Liu, Shangchao Du, Wuping Liao,