| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7810896 | Journal of Molecular Structure | 2013 | 7 Pages |
Abstract
A new derivative of polyether ionophore salinomycin was obtained as a result of a rearrangement catalysed by sulphuric acid in two-phase medium of water/methylene chloride solution. The new isomer was fully characterized by multinuclear 2D NMR, NOESY and MALDI-TOF. The properties of the new compound were additionally study by semiempirical (PM5) and DFT (B3LYP) methods. A potential mechanism of the rearrangement was also proposed.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
RadosÅaw Pankiewicz,