Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7899583 | Journal of Non-Crystalline Solids | 2018 | 8 Pages |
Abstract
We present a method for high temperature stabilization of bulk amorphous aluminium oxide. The stabilization is achieved by dispersing polysilane dendritic molecules in aluminium hydroxide gel, which upon thermal treatment gives amorphous aluminium oxide stable up to 900â¯Â°C. The dispersed macromolecules covalently bind to the alumina matrix and induce homogeneously distributed strain fields that keep the alumina amorphous. The thermal conversion of the precursor system was followed by thermogravimetry with an evolved gas analysis, infrared spectroscopy and 29Si NMR. The amorphous structure of aluminium oxide was confirmed with an X-ray and electron diffraction. Additionally, the amorphous state was supported by presence of penta-coordinated aluminium detected by 27Al NMR and a low bandgap measured by a UV-visible absorption spectroscopy.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Andraž MavriÄ, Mattia Fanetti, Gregor Mali, Matjaz Valant,