Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7899595 | Journal of Non-Crystalline Solids | 2018 | 7 Pages |
Abstract
The by-product silicon tetrachloride (SiCl4) was usually obtained from polysilicon industry and was a cheaper alternative precursor. An economic method to produce silica aerogel using silicon tetrachloride under ambient pressure drying was presented in this work, which can also solve the pollution problem during the by-product silicon tetrachloride treatment process. The prepared aerogel samples were characterized by scanning electron microscopy, Brunauer-Emmett-Teller analysis, thermal conductivity analysis, contact angle test, Fourier transform infrared spectroscopy and thermogravimetric analysis. It was found that the molar ratio of H2O/SiCl4 could affect the properties of aerogels seriously. The density and thermal conductivity first decreased and then increased as the molar ratio increased from 13 to 32. The porosity showed an opposite trend with the density. Silica aerogel with high specific surface area (856.7â¯m2/g), low density (0.077â¯m3/g) and low thermal conductivity (0.0213â¯W/m·k) were obtained at the optimal conditions when the molar ratio was 25. The resulting aerogel is also mesoporous material with super hydrophobicity and have a huge application in thermal insulation field.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Ting Zhou, Lunlun Gong, Xudong Cheng, Yuelei Pan, Congcong Li, Heping Zhang,