Article ID Journal Published Year Pages File Type
7902086 Journal of Non-Crystalline Solids 2014 5 Pages PDF
Abstract
A series of Ce3 +/Sm3 + doped glasses were prepared in this study and their luminescence properties were analyzed. A combination of blue and orange-red emission band was observed from these glasses, and tunable white light emission could be observed by adjusting concentration ratio of Ce3 + to Sm3 + under UV light excitation. Energy transfer (ET) from Ce3 + to Sm3 + is discovered by directly observing significant overlap of the excitation spectrum of Sm3 + and the emission spectrum of Ce3 + ions. The energy transfer from Ce3 + to Sm3 + via a dipole-dipole mechanism was confirmed by the luminescence spectra, the decay lifetime and the calculation of energy transfer efficiency of the glasses. Based on the results in this study, the Ce3 +/Sm3 + doped glasses could be used as a potential matrix material for ultraviolet light emitting diode (LED) chip based white LEDs.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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