Article ID Journal Published Year Pages File Type
8020028 Materials Letters 2014 4 Pages PDF
Abstract
A novel red-emitting Ba2ScO3F:Eu3+ phosphor was prepared by high-temperature solid-state reaction method. The structure and luminescence properties of the obtained phosphors were investigated. The crystallographic occupancy of Eu3+ in Ba2ScO3F was studied and verified to be the site of Sc3+ ions. Photoluminescence of the optimized Ba2Sc0.94O3F:0.06Eu3+ phosphor showed that the phosphor can be efficiently excited by ultraviolet (395 nm) and blue (464 nm) light, and exhibits an intense red emission at 612 nm (due to 5D0→7F2 electric dipole transition of Eu3+ ions). The dependence of the luminescence intensity on temperatures was measured, and showed a satisfactory thermal quenching effect. These results suggest that the phosphor could be a potential for applications in w-LEDs.
Related Topics
Physical Sciences and Engineering Materials Science Nanotechnology
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