The fourth spectrum of platinum (Pt IV): Determination of the 5d7, 5d66s and 5d66p configurations

The spectrum of three times ionized platinum, Pt IV, was investigated in the 530-1800 Å wavelength region. The analysis has resulted in the determination of the 5d7, 5d66s and 5d66p configurations. Seventeen of 19 theoretically possible 5d7 levels, 58 of 63 possible 5d66s levels and 162 of 180 possible 5d66p levels have been established. The levels are based on 1478 classified spectral lines. The level structure and transition probabilities were calculated by means of the orthogonal operators method. The energy parameters have been determined by the least squares fit to the observed levels. Calculated energy values and LS-compositions, as well as gA values obtained from the fitted parameter values are presented.