Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8329113 | International Journal of Biological Macromolecules | 2018 | 42 Pages |
Abstract
This article addresses the elegant and green approach for fabrication of bio-based poly (lactic acid) (PLA)/cellulose nanocrystal (CNCs) bionanocomposite foam (PLA/CNC) with cellular morphology and hydrophobic surface behavior. Highly porous (porosity >80%) structure is obtained with interconnected pores and the effect of CNCs in the cell density (Nf) and cell size of foams are thoroughly investigated by morphological analysis. The thermo-mechanical investigations are performed for the foam samples and almost â¼1.7 and â¼2.2 fold increase in storage modulus is observed for the compressive and tensile mode respectively. PLA/CNC based bionanocomposite foams displayed similar thermal stability as base PLA foam. Detailed investigations of decomposition behavior are studied by using hyphenated thermogravimetric analysis-fourier transmission infrared spectroscopy (TGA-FTIR) system. Almost â¼13% increment is observed in crystallinity at highest loading of CNCs compared to neat counterpart. To investigate the splitting and spreading phenomenon of the wettability of the samples, linear model is used to find the Young's contact angle and contact angle hysteresis (CAH). Besides, â¼6.1 folds reduction in the density of PLA and the nanocomposite foams compared to PLA carries much significance in specialized application areas where weight is an important concern.
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Authors
Shasanka Sekhar Borkotoky, Prodyut Dhar, Vimal Katiyar,