Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8942815 | International Journal of Hydrogen Energy | 2018 | 9 Pages |
Abstract
By surface-decorating PtTiO2 hybrid catalyst with MoS2 nanosheets, we prepared a new MoS2/PtTiO2 ternary system as high-performance photocatalysts. The ternary MoS2/PtTiO2 outperforms both the binary MoS2TiO2 and PtTiO2 systems in photocatalytic hydrogen evolution with an AQY (apparent quantum yield) value of 12.54% at 420Â nm, owing to the unique ternary design that creates more efficient electron transport path and electron-hole separation mechanism. Electrochemical characterization showed that the MoS2/PtTiO2 ternary electrode afford an efficient pathway of photo-excited electrons from TiO2 to surface-decorated Pt nanoparticles using MoS2 and internal Pt nanoparticles as bridges, thus significantly promoting electron transfer, reducing the system overpotential and leading to the activation of more reactive sites. This internal electron transfer pathway (TiO2 â Pt (internal) â MoS2 â Pt (surface)) eliminates the need of other metal cocatalysts because the Pt nanoparticles play two roles of storing the conduction band electrons of TiO2 and acting as co-catalyst for reduction of protons to hydrogen. This unique ternary metal-semiconductor heterojunction for efficient photocatalytic hydrogen evolution provides a meaningful reference for reasonable design of other hybrid photocatalysts.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Shasha Li, Tingting Pu, Junjie Wang, Xueyou Fang, Yanfei Liu, Shifei Kang, Lifeng Cui,