Predicting whether a material is ductile or brittle

In this paper we discuss the various models that have been used to predict whether a material will tend to be ductile or brittle. The most widely used is the Pugh ratio, G/K, but we also examine the Cauchy pressure as defined by Pettifor, a combined criterion proposed by Niu, the Rice and Thomson model, the Rice model, and the Zhou-Carlsson-Thomson model. We argue that no simple model that works on the basis of simple relations of bulk polycrystalline properties can represent the failure mode of different materials, particularly where geometric effects occur, such as small sample sizes. Instead the processes of flow and fracture must be considered in detail for each material structure, in particular the effects of crystal structure on these processes.