Power-to-Gas: Storing surplus electrical energy. Study of catalyst synthesis and operating conditions

Energy storage is needed in order to sustain the energy system on renewable energies like wind and solar power. Power-to-Gas (PtG) is a technology that enables the storage of the renewable electricity in a chemical carrier such as hydrogen, via water electrolysis, or methane, via carbon dioxide methanation. In this work a series of catalysts based on nickel and alumina, the catalyst commonly employed for carbon dioxide methanation, have been synthesised employing different calcination temperatures to study the influence of this parameter in the activity of the catalysts. As a result of this study 673 K was determined as the most suitable Moreover, the catalysts have also been tested at different pressures to determine the most suitable operating pressure. Although due to Le Chatelier's Principle a higher pressure results in an increasing yield, the study carried out proved that 10 bar is the most suitable pressure as the difference in the yield when increasing the pressure it is not high enough taking into account the costs and risks associated with higher pressures.