| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9565937 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
Addition of a phosphenium dramatically improved the reaction yields in the carboxylation of arenes by formic acid catalyzed by Pd(II). Control experiments revealed that the majority of the phosphenium triflate was converted to a mixed anhydride of phosphonic acid and formic acid (7), which however did not substitute for the phosphenium to improve the reaction yield.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ken Sakakibara, Makoto Yamashita, Kyoko Nozaki,