Article ID Journal Published Year Pages File Type
9605594 Journal of Photochemistry and Photobiology A: Chemistry 2005 6 Pages PDF
Abstract
Proton transfer in organized assembly has been investigated by steady-state and picosecond time-resolved fluorescence spectroscopy. Pyranine has been incorporated into the functionalized Langmuir-Blodgett (LB) films of octadecylamine. This paper is the first example of investigating proton transfer involving pyranine in the restricted geometry of functionalized LB films. Time-resolved fluorescence spectra of pyranine in LB film matrices show that as deprotonation occurs the PyOH* band decays and the PyO−* band builds up. It is observed that the proton transfer reactions in restricted geometry can be monitored by choosing proper parameters.
Related Topics
Physical Sciences and Engineering Chemical Engineering Bioengineering
Authors
, ,