Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9605594 | Journal of Photochemistry and Photobiology A: Chemistry | 2005 | 6 Pages |
Abstract
Proton transfer in organized assembly has been investigated by steady-state and picosecond time-resolved fluorescence spectroscopy. Pyranine has been incorporated into the functionalized Langmuir-Blodgett (LB) films of octadecylamine. This paper is the first example of investigating proton transfer involving pyranine in the restricted geometry of functionalized LB films. Time-resolved fluorescence spectra of pyranine in LB film matrices show that as deprotonation occurs the PyOH* band decays and the PyOâ* band builds up. It is observed that the proton transfer reactions in restricted geometry can be monitored by choosing proper parameters.
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Authors
Krishanu Ray, Hiroo Nakahara,