Article ID Journal Published Year Pages File Type
9607569 Journal of Photochemistry and Photobiology C: Photochemistry Reviews 2005 16 Pages PDF
Abstract
The Photo-Claisen reaction is one of the classical photochemical rearrangements of aromatic molecules and is mechanistically related to the Photo-Fries reaction. It consists in the formation of ortho- and para-substituted phenols from phenyl ethers after irradiation. The reaction mechanism involves a singlet radical pair within a solvent cage and because of its simplicity constitutes a suitable model for the study of analogous reactions.
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Physical Sciences and Engineering Chemical Engineering Bioengineering
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