Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9617772 | Microporous and Mesoporous Materials | 2005 | 10 Pages |
Abstract
A series of sulphated ZrO2-TiO2 mixed oxide with different nominal sulphate loadings in the range of 2-15Â wt.% was prepared and characterized for their structural properties, surface acidity and benzene isopropylation activity. The catalyst with 10Â wt.% nominal sulphate loading showed highest surface area and uniform pore size distributions. Surface acidity, measured by NH3-TPD method, showed increase in acidity with sulphate loading and the 10Â wt.% sulphate loaded catalyst showed highest acidity. The activities of these catalysts were tested for isopropylation of benzene to cumene using 2-propanol as the alkylating agent. The 10Â wt.% sulphate-loaded catalyst also showed highest activity for this reaction with â¼97% cumene selectivity. The higher activity of this catalyst was attributed to its higher acidity.
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Authors
D. Das, H.K. Mishra, N.C. Pradhan, A.K. Dalai, K.M. Parida,