Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9617790 | Microporous and Mesoporous Materials | 2005 | 7 Pages |
Abstract
SBA-3 with pore sizes of 22-25Â Ã
has been successfully prepared by TEOS liquid phase deposition on the pristine SBA-3 with a pore size of ca. 27Â Ã
. After the first TEOS modification, the resulting sample (Name: M1/SBA-3) shows obvious changes in textural properties. As compared to SBA-3, M1/SBA-3 has negligible micropores, its BET surface area and pore volume decrease by 24% and 40% respectively, its wall thickness increases from 15Â Ã
to 22Â Ã
and its pore size decreases from 27Â Ã
to 23Â Ã
. The presence of ethoxysilyl groups on M1/SBA-3 is supported by FTIR and carbon content measurement, and their loading amount is estimated to be ca. 5.7Â wt% by TGA. The second TEOS modification is less efficient to change the textural properties of SBA-3 owing to its lower loading (ca. 1.3Â wt%).
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Fengxi Chen, Shoucang Shen, Xiao-Jun Xu, Rong Xu, Fethi Kooli,