Article ID Journal Published Year Pages File Type
9617799 Microporous and Mesoporous Materials 2005 5 Pages PDF
Abstract
This work studied the ion exchange of Cu2+, Ni2+, Pb2+ and Zn2+ into an analcime (ANA) in the temperature range 298-333 K. The analcime was produced from an economically available Thai perlite. The selectivity sequence for ions entering analcime in its as-synthesized sodium form was Pb2+ > Cu2+ > Zn2+ > Ni2+, as indicated by values of ΔG0. The results demonstrated that the enthalpy of cation hydration determined the selectivity of the zeolite. ΔS0 values were related to changes in water content. A comparison of the selectivity series for Pb, Cu, Ni, and Zn cation uptake into analcime to those of other zeolites shows similar trends.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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