Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9675741 | Colloids and Surfaces A: Physicochemical and Engineering Aspects | 2005 | 7 Pages |
Abstract
The Surface Evolver was used to compute the equilibrium microstructure of random soap foams with bidisperse cell-size distributions and to evaluate topological and geometric properties of the foams and individual cells. The simulations agree with the experimental data of Matzke and Nestler for the probability Ï(F) of finding cells with F faces and its dependence on the fraction of large cells. The simulations also agree with the theory for isotropic Plateau polyhedra (IPP), which describes the F-dependence of cell geometric properties, such as surface area, edge length, and mean curvature (diffusive growth rate); this is consistent with results for polydisperse foams. Cell surface areas are about 10% greater than spheres of equal volume, which leads to a simple but accurate relation for the surface free energy density of foams. The Aboav-Weaire law is not valid for bidisperse foams.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Colloid and Surface Chemistry
Authors
Andrew M. Kraynik, Douglas A. Reinelt, Frank van Swol,