Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9769843 | Journal of Molecular Structure | 2005 | 4 Pages |
Abstract
The crystal structure of MoO(O2)2(H2O)(hmpa), hmpa=hexamethylphosphoramide, has been reassessed and corrected as one of the axial parameters (namely the c-axis) was reported incorrectly. This resulted in significant differences in the internal geometry of the molecule, notably an decreased O-O atom distance (â0.03Â Ã
) in the metal-bonded peroxo ligands. Crystal packing forces and a flat bending potential of the Mo-O-P angle accounts for discrepancies between theory and experimental structures.
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Authors
Craig A. Bayse, Ampa Jimtaisong, Anil K. Kandalam, Rudy L. Luck, Ravindra Pandey, Mark J. Stevens,