Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9769845 | Journal of Molecular Structure | 2005 | 5 Pages |
Abstract
Reaction of K3[Fe(CN)6] with [Cu(tn)2](ClO4)2 (tn=1,3-diaminopropane) leads to a novel mixed cyano and tn bridged three-dimensional (3D) bimetallic assembly [Cu2II(tn)2][FeII(CN)6]·H2O (1), in which each [Fe(CN)6]4â anion connects six copper(II) cations via six CNâ groups, whereas each copper(II) cation is linked to three [Fe(CN)6]4â ions and two other copper(II) ions through Cu-NC-Fe and Cu-tn-Cu linkages, respectively. Magnetic studies reveal weak antiferromagnetic interactions between the nearest CuII (S=1/2) ions through the diamagnetic [Fe(CN)6]4â anion.
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Authors
Xiao-Ping Shen, Yi-Zhi Li, Ai-Hua Yuan, Zheng Xu,