Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9769904 | Journal of Molecular Structure | 2005 | 4 Pages |
Abstract
A new three-dimensional metal-organic framework, [Zn2(BTDA)(bpy)(H2O)]·0.5bpy (1) (BTDC=3,3â²,4,4â²-benzophenone tetracarboxylate, bpy=4,4â²-bipyridine), has been prepared with the contemporary use of two different kinds of ligands, the rigid 4,4â²-bipyridyl (bpy) and the V-shaped flexible multi-carboxylic ligands H4BTDC, and characterized by single-crystal X-ray diffraction analysis. The three-dimensional framework is assembled from bpy-pillared two-dimensional sheets and contains one-dimensional rhombus channels with the dimensions of 4.06Ã12.07 Ã
. Furthermore, compound 1 shows blue photoluminescent property at room temperature.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jun Hong,