Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9769927 | Journal of Molecular Structure | 2005 | 9 Pages |
Abstract
By means of base-catalysed condensation of 1-acyl-/1,1â²-diacylferrocenes (acylformyl or acetyl) with 3-formyl- and 3,7-diacetylphenothiazines a series of novel mono- and bis-chalcones were prepared. The enhanced reactivity of the enolate anions of the mono-chalcone intermediates relative to that of the enolates of the corresponding diacetyl-substituted precursor was interpreted by the electron-releasing effect of the ferrocenyl- or phenothiazinyl group present in the β position of the enone subunit. The structures of the novel products were evidenced by IR, 1H and 13C NMR spectroscopy including 2D-COSY, 2D-HSQC and 2D-HMBC measurements.
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Authors
Tamás Lovász, György Túrós, Luiza GÄinÄ, Antal Csámpai, Dávid Frigyes, Balázs Fábián, Ioan A. Silberg, Pál Sohár,