Article ID Journal Published Year Pages File Type
9769950 Journal of Molecular Structure 2005 5 Pages PDF
Abstract
A new Zn(II) complex, [Zn(pyz)(H2O)4]pht (1) (pyz=pyrazine; pht=1,2-benzenedicarboxylate) has been hydrothermally synthesized and characterized. Complex 1 features a novel polar 3D framework with a 1D polycationic chain [Zn(pyz)(H2O)4]n2n+, between which pht2− dianions are encapsulated via the supramolecular interaction. Its powder SHG is of about three times as large as that of KH2PO4.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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