Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9769969 | Journal of Molecular Structure | 2005 | 4 Pages |
Abstract
Hydrothermal reaction of copper(II) acetate, 2,2â²-bipyridine (bipy) and NH4VO3 at 170 °C lead to a new layered polyoxovanadate with organically covalent-bonded copper(II) complex, Cu2(bipy)2V6O17 (1). Cu2(bipy)2V6O17 (1) is a new copper(II) vanadium(V) oxide featuring a new layered architecture, in which the V2O7 dimeric units and the cyclic tetranuclear V4O12 cluster units are interconnected via corner sharing into a unique one-dimensional {V6O17}4â anionic chain, such chains are further bridged by {Cu(bipy)}2+ complex cations into a ã010ã organic-inorganic hybrid layer.
Related Topics
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Authors
Jin-Yu Xie, Jiang-Gao Mao,