Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9769978 | Journal of Molecular Structure | 2005 | 9 Pages |
Abstract
Mass spectra of several azonaphthols and related Schiff bases containing intramolecular hydrogen bonding (IHB) are interpreted in respect of their keto-enol tautomerism. It is shown that in gas phase the enol-like tautomer strongly predominates. In the azodyes the existing IHB is very weak, while in the corresponding Schiff bases it is strong enough and determines the fragmentation pathway.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Daniela Nedeltcheva, Boryana Damyanova, Simeon Popov,