Article ID Journal Published Year Pages File Type
9769978 Journal of Molecular Structure 2005 9 Pages PDF
Abstract
Mass spectra of several azonaphthols and related Schiff bases containing intramolecular hydrogen bonding (IHB) are interpreted in respect of their keto-enol tautomerism. It is shown that in gas phase the enol-like tautomer strongly predominates. In the azodyes the existing IHB is very weak, while in the corresponding Schiff bases it is strong enough and determines the fragmentation pathway.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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