Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770025 | Journal of Molecular Structure | 2005 | 6 Pages |
Abstract
A new mixed-valence hexadecavanadate H2[C(CH2OH)3NH3]0.5[Cd(phen)3] {[Cd(H2O)(phen)2]2(V16O38Cl)}0.5{[Cd(H2O)(phen)2]2(V16O39Cl)}0.5·2H2O (1) (phen=1, 10â²-phenanthroline) has been synthesized under the hydrothermal conditions. Its structure was established by single-crystal X-ray diffraction. Compound 1 crystallizes in the triclinic space group Pâ1 with cell parameters of a=15.943(2) Ã
, b=17.744(2)Â Ã
, c=21.420(3)Â Ã
, α=82.955(2)°, β=79.479(2)°, γ=65.052(2)°, V=5394.3(12) Ã
3, Z=2. It exhibits an unusual 2D supramolecular layer in which dimers of organic small molecules act as connectors.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Baoxia Dong, Yanhui Chen, Jun Peng, Yumei Kong, Zhangang Han,