Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770070 | Journal of Molecular Structure | 2005 | 5 Pages |
Abstract
The Raman spectra of the two dimensional layered polymer compounds, M(2APM)2Mâ²(CN)4 {where M=Mn or Cd; and Mâ²=Ni or Pt; 2APM=2-aminopyrimidine} are reported in the 70-4000Â cmâ1 region. Vibrational data suggests that compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Mâ²(CN)4â2 ions bridged by M(2APM)2+2 cations. 2-Aminopyrimidine was coordinated to M(II) through one of the nitrogen atom of its heterocycle ring. Vibrational assignments are given for the bands arising from the tetracyanometallate layers and coordinated 2APM.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sevim Akyuz, Tanil Akyuz,