Article ID Journal Published Year Pages File Type
9770070 Journal of Molecular Structure 2005 5 Pages PDF
Abstract
The Raman spectra of the two dimensional layered polymer compounds, M(2APM)2M′(CN)4 {where M=Mn or Cd; and M′=Ni or Pt; 2APM=2-aminopyrimidine} are reported in the 70-4000 cm−1 region. Vibrational data suggests that compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with M′(CN)4−2 ions bridged by M(2APM)2+2 cations. 2-Aminopyrimidine was coordinated to M(II) through one of the nitrogen atom of its heterocycle ring. Vibrational assignments are given for the bands arising from the tetracyanometallate layers and coordinated 2APM.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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