Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770139 | Journal of Molecular Structure | 2005 | 10 Pages |
Abstract
Two symmetric dinuclear copper (II) macrocyclic complexes ([Cu2L](ClO4)2 and [Cu2Lâ²](ClO4)2) were unexpectedly obtained by the cyclocondensation between N,Nâ²-bis(3-formyl-5-n-butylsalicylidene)ethylenediimine and 1,3-diaminopropane in the presence of copper (II) perchlorate and characterized by some physical methods. Both complexes were determined by X-ray diffraction techniques. DFT theoretical calculation was used to discuss the structure and to assign the IR spectra of the cation of the complex ([Cu2L](ClO4)2, the complete vibration spectral analysis was performed. A good agreement is obtained between DFT theoretical calculation results and the experimental data for the complex ([Cu2L](ClO4)2.
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Authors
H. Zhou, Z.H. Peng, Z.Q. Pan, D.C. Li, B. Liu, Z. Zhang, R.A. Chi,