Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770205 | Journal of Molecular Structure | 2005 | 7 Pages |
Abstract
A complex of 5,5â²-dibromo-2,2â²-biphenol with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene hydroiodide has been studied by X-ray diffraction, FT-IR, and 1HNMR spectroscopy. In the crystal structure, the iodide anion is hydrogen-bonded to the MTBDH+ cation and to two hydroxyl groups of two 5,5â²-dibromo-2,2â²-biphenol molecules. In chloroform and acetonitrile the structure of the complex assumes a new structure due to almost complete dissociation of the protonated MTBD molecule. In chloroform the MTBDH+ cation is hydrogen bonded to 5,5â²-dibromo-2,2â²-biphenol whereas in acetonitrile it is free and solvated by the solvent. In both cases the 5,5â²-dibromo-2,2â²-biphenol molecule is hydrogen bonded to the iodide anion. In chloroform the iodide ion interacts strongly with the solvent.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Grzegorz Wojciechowski, MaÅgorzata Ratajczak-Sitarz, Andrzej Katrusiak, Bogumil Brzezinski,