Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770259 | Journal of Molecular Structure | 2005 | 5 Pages |
Abstract
Optical and EPR investigations of chromium and nickel doped zinc phosphate glasses are carried out at room temperature to evaluate crystal field, spin-Hamiltonian and bonding parameters. For Cr3+ ion, the site symmetry is ascribed to a distorted octahedron, whereas the Ni2+ ion is located in a near octahedral site. In addition, the bonding parameters suggest covalent nature for Cr3+ and a moderate covalent nature for Ni2+ in the zinc phosphate glasses.
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Authors
R.V.S.S.N. Ravikumar, J. Yamauchi, A.V. Chandrasekhar, Y.P. Reddy, P. Sambasiva Rao,