Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770357 | Journal of Molecular Structure | 2005 | 5 Pages |
Abstract
A dimeric TTF derivative of bis{2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4-(methylsulfanyl)-5-(methylenesulfanyl)-1,3-dithiole} (1) was synthesized and characterized. The sulfur atom of a methylthio group interacts with CC double bond of the neighboring TTF moiety exhibiting a S-Ï interactions within a molecular chain. The molecules are further assembled to a 2D structure by an Sâ¯S interaction (3.3441(17) Ã
). Open and folded model for the molecular conformation is discussed based on the results measured in the solid state (crystal structure) and in solution (cyclic voltammogram).
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Authors
Li-Hui Cao, Yong Zhang, Jie Dai, Hai-Hong Lin, Wen Lu, Wen-Juan Guo,