Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770383 | Journal of Molecular Structure | 2005 | 5 Pages |
Abstract
Infrared multiple-angle incidence resolution spectrometry (MAIRS) has been employed to characterize a thin cast film of tripeptide-induced lipid (Leu3) prepared on a germanium substrate. Leu3 molecules are designed to spontaneously interact with each other by hydrogen bonding via amide groups and leucine fastener. The molecular aggregate of Leu3 is known to have a unique property that it forms a flexible polymer-like film, although the molecules are not covalently bonded. Infrared MAIRS has revealed that a Leu3 cast film forms the parallel β-sheet structure, and the amide groups have a specific molecular orientation, probably because the molecules would have strong interaction with the substrate. Further, it has experimentally been confirmed that the amide B band is a Fermi resonance band derived from the amide II mode powered by amide A mode by the analysis of the MAIRS spectra.
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Authors
Takeshi Hasegawa, Junzo Umemura, Norihiro Yamada,