Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9770437 | Journal of Molecular Structure | 2005 | 7 Pages |
Abstract
Tris(cyclopentadienyl)scandium ScCp3 was isolated in Ar-matrices (20 K) and the structure of monomeric ScCp3 was studied using infrared spectrometry. When compared with the spectra and results of density functional calculations, the matrix-isolated ScCp3 was found to have a structure where all three of the cyclopentadienyl rings coordinate to scandium in η5 coordination, Sc(η5-Cp)3, which is different from the structure in the solid phase. Moreover, a stable dimer structure was estimated to be [(η5-Cp)2Sc(μ-η1-Cp:η1-Cp)]2, using density functional calculations.
Related Topics
Physical Sciences and Engineering
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Authors
Jun Miyazaki, Yasuhiro Yamada,