Article ID Journal Published Year Pages File Type
10567459 Journal of Power Sources 2011 5 Pages PDF
Abstract
► BH4− oxidation in nonaqueous solvents to prevent detrimental hydrolysis to H2. ► Many nonaqueous solvents react with BH4− to produce H2 or do not solubilize it. ► Only DMSO and DMF were suitable solvents for BH4−. ► DMSO and DMF prevent bulk, not surface, BH4− decomposition to H2, but decrease electron recovery. ► MeOH does not improve electron recovery by acting as a ligand to stabilize oxidized B.
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Physical Sciences and Engineering Chemistry Electrochemistry
Preview
Electro-oxidation of BH4− in dimethylsulfoxide and dimethylformamide studied by rotating disk electrode voltammetry
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