Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10567630 | Journal of Power Sources | 2011 | 7 Pages |
Abstract
ⶠThe dependence of the degradation kinetics in Ni-CGO (cerium-gadolinium oxide) solid oxide fuel cell (SOFC) anodes upon KCl salt evaporation is demonstrated operando with a custom built versatile reactor system. Fast changes in the charge transfer and ohmic resistance are observed in the anodes fuelled with a gas mixture containing a high KCl vapor concentration. Rapid condensation of salt vapors into the porous anode and partial delamination of the anode from the electrolyte surface because of salt deposits inside the porous anode is observed. The flexibility to produce vapor-aerosol mixtures with different concentrations and particle size distributions is proved, and suitability of these aerosols for anode testing in long term fuel cell test is evaluated.
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Authors
Gunnar Nurk, Peter Holtappels, Renato Figi, Jörg Wochele, Marco Wellinger, Artur Braun, Thomas Graule,