Optimisation of processing and microstructural parameters of LSM cathodes to improve the electrochemical performance of anode-supported SOFCs

Results from electrochemical measurements performed between 700 and 900 °C with H2 (3 vol.% H2O) as fuel gas and air as the oxidant showed that the performance was the highest using an LSM/YSZ mass ratio of 50/50. A further increase of the electrochemical performance was obtained by increasing the grain size of the outer cathode current collector layer: the highest performance was achieved with non-ground LSM powder. In addition, it was found that the thickness of the cathode functional layer and cathode current collector layer also affects the electrochemical performance, whereas no obvious detrimental effects occurred with the different qualities of YSZ powder for the cathode functional layer. The highest performance, i.e. 1.50 ± 0.05 A cm−2 at 800 °C and 700 mV, was obtained with a cathode functional layer, characterised by an LSM/YSZ mass ratio of 50/50, a d90 of the LSM powder of 1.0 μm, non-calcined YSZ powder, and a thickness of about 30 μm, and a cathode current collector layer, characterised by d90 of the LSM powder of 26.0 μm (non-ground), and a thickness of 50-60 μm. Also interesting to note is that the use of non-ground LSM for the cathode current collector layer and non-calcined YSZ powder for the cathode functional layer obviously simplifies the production route of this type of fuel cell.