Article ID Journal Published Year Pages File Type
10569788 Inorganic Chemistry Communications 2005 4 Pages PDF
Abstract
[(2,4,6-tBu3C6H2)InPSi(tBu)3]2 was synthesized and X-ray crystallographically characterized as the first dimeric phosphanylidene indane with three-coordinate indium and phosphorus atoms. The analogous reaction with the gallium derivative and the smaller triisopropylsilyl ligand leads to the formation of (2,4,6-tBu3C6H2)2GaP(H)SiiPr3 as a monomeric phosphanylgallane with a three-coordinate gallium atom.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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