Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10570116 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
A new dinuclear copper(II) complex [Cu2(μ1,1-NCO)2(NCO)2(dpyam)2] (dpyam = di-2-pyridylamine) has been synthesized and characterized by X-ray diffraction. Two N-bonded cyanato ligands bridge two copper ions in an end-on fashion and two others act as the N-bonded terminal ligands. The copper ion has a distorted square-pyramidal environment. The magnetic susceptibility, measured from 5 to 300 K, has revealed a weak ferromagnetic interaction between the Cu(II) atoms with a singlet-triplet energy gap (J) of 6.03 cmâ1.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sujittra Youngme, Jaturong Phatchimkun, Unchulee Suksangpanya, Chaveng Pakawatchai, Gerard A. van Albada, Jan Reedijk,