Article ID Journal Published Year Pages File Type
10570116 Inorganic Chemistry Communications 2005 4 Pages PDF
Abstract
A new dinuclear copper(II) complex [Cu2(μ1,1-NCO)2(NCO)2(dpyam)2] (dpyam = di-2-pyridylamine) has been synthesized and characterized by X-ray diffraction. Two N-bonded cyanato ligands bridge two copper ions in an end-on fashion and two others act as the N-bonded terminal ligands. The copper ion has a distorted square-pyramidal environment. The magnetic susceptibility, measured from 5 to 300 K, has revealed a weak ferromagnetic interaction between the Cu(II) atoms with a singlet-triplet energy gap (J) of 6.03 cm−1.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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