Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10570380 | Inorganic Chemistry Communications | 2010 | 6 Pages |
Abstract
The hybrid complex consist of molybdenylacetylacetonate complex covalently linked to a lacunary Keggin-type polyoxometalate, was synthesized and characterized by elemental analysis, SEM, diffuse reflectance UV-Vis and FT-IR spectroscopic methods. The hybrid complex, [MoO2(acac)-POM], was used for alkene epoxidation with tert-BuOOH in 1,2-dichloroethane as solvent. This heterogeneous catalyst was reused several times in the oxidation of cyclooctene.
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Authors
Majid Moghadam, Valiollah Mirkhani, Shahram Tangestaninejad, Iraj Mohammadpoor-Baltork, Maedeh Moshref Javadi,